Atmosphere‐free activation methodology for holey graphene/cellulose nanofiber‐based film electrode with highly efficient capacitance performance

نویسندگان

چکیده

An efficient chamber-induced activation method was applied for the preparation of holey graphene/cellulose nanofiber-based film with high specific surface area (SSA) and multiple channels through graphene nanosheets. With cellulose nanofiber (CNF) simultaneously serving as “dispersing agent,” “spacer,” “activating oxide (GO) nanosheets are perforated by pyrolysis gas from CNF in confined space inside hybrid films, uniformly dispersed, sandwiched between networks less agglomeration restacking. Additionally, we have proved that H2O H2 primarily responsible etching GO/CNF film. As content increases, mesoporosity activated reduced (A-RGO/CNF) show more nanopore perforations. Benefitting SSA, density, moderate mesoporosity, abundant ion diffusion nanosheets, A-RGO/CNF exhibits highest capacitance 323 (236) F g−1 (F cm−3) at 1 A g−1. For A-RGO5/CNF5 containing half GO, an excellent comprehensive electrochemical performance including superior rate (208 (160) 60 g−1) is exhibited. Moreover, electrode all-solid-state flexible symmetric supercapacitor delivers a 250 (193) This study provides novel idea graphene-based electrodes. The strategy employing agent” also offers new vision assembly homogeneous nanohybrid material utilization gas.

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ژورنال

عنوان ژورنال: Carbon energy

سال: 2022

ISSN: ['2096-9570', '2637-9368']

DOI: https://doi.org/10.1002/cey2.229